2024
DOI: 10.1002/smtd.202400715
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Inside Ceramics and Between MgO Grains: Solid‐State Synthesis of Intergranular Semiconducting or Magnetic Spinels

Thomas Schwab,
Korbinian Aicher,
Gregor A. Zickler
et al.

Abstract: Configurations of composite metal oxide nanoparticles are typically far off their thermodynamic equilibrium state. As such they represent a versatile but so far overlooked source material for the intergranular solid‐state chemistry inside ceramics. Here, it is demonstrated how the admixture of Fe3+ and In3+ ions to MgO nanoparticles, as achieved by flame spray pyrolysis, can be used to engage ion exsolution, phase separation, and subsequent spinel formation inside the network of diamagnetic and insulating MgO … Show more

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