Actual plan of research work was proposed for systematic investigating in the eld of photogalvanic cell (PG cell) for solar energy transformation. It was necessary and proposed to carry out experimental work under the solar parameters. The object of the research work is to enhance the solar energy conversion in to electricity and store through photogalvanic cells. Various parameters were studied in a photogalvanic cell having D-Xylose + MB + Brij-35 + NaLS PGS (photo galvanic system). The open circuit voltage and photopotential were observed 921.00 mV and 698.00 mV respectively for D-Xylose + MB + Brij-35 + NaLS PGS. The maximum photocurrent and short circuit current were observed 311µA and 245.0 µA respectively in D-Xylose + MB + Brij-35 + NaLS PGS. The equilibrium photocurrent and current at power point were observed 243.0 µA and 142.0 µA respectively in D-Xylose + MB + Brij-35 + NaLS PGS. The ll factor and conversion e ciency were observed 0.4521 and 0.6769% respectively in D-Xylose + MB + Brij-35 + NaLS PGS. The impact of solar energy was studied by vary the various parameters in PGS. The D-Xylose + MB + Brij-35 + NaLS PGS performance was found 126.00 minutes in absence of light on illumination of 90.0 minutes. On basis of above obtained values, the mixed surfactants (NaLS + Brij-35)have experimentally proved the e cient system as desired object of research with special reference to enhance electrical out and storage of solar energy.