Interfacial reactions between titanium–copper melt and crucible oxides

Joining of silicon nitride ceramic to oxygen‐free copper using Ag–Cu–TiH2 filler

“…The grain boundary phases with the composition Y–Si–Mg–O–N are formed by the reaction of SiO 2 , Si 3 N 4 , MgO, and Y 2 O 3 . It has been reported that Y 2 O 3 and MgO are commonly used as crucibles for high‐temperature melting and casting of Ti or Ti‐based alloys, 61–63 thus implying that the reaction between MgO and Y 2 O 3 with Ti at brazing temperature is inconsequential. Referring to the reaction of Ti with SiO 2 and Si 3 N 4 , the reaction of Ti with Y–Si–Mg–O–N is shown in reaction (2).…”

Interfacial Adsorption and Electron Properties of Water Molecule/Cluster on Anatase TiO2(101) Surface: Raman and DFT Investigation

“…However, only the rutile and anatase forms can stably exist in the natural environment. Moreover, previous studies have confirmed that it is easier to form the anatase structure in the nanoscale, with the most stable and easily exposed surface of (101). , The service environment of titanium mostly involves the interface of metal/water; , in addition, the physicochemical properties of solid materials are strongly dependent on the adsorbed molecules. − Shi et al hold the view that water adsorption on CuAl 2 O 4 surfaces leads to the decreases of the work function at low water coverage . Faye et al demonstrated that H 2 O contaminants could act as a barrier to the adsorption of heterogeneous molecules .…”