In this paper, an improved complex-valued convolutional neural network (CvCNN) structure to be placed at the received side is proposed for nonlinearity compensation in a coherent optical system. This complex-valued global convolutional kernel-assisted convolutional neural network equalizer (CvGNN) has been verified in terms of Q-factor performance and complexity compared to seven other related nonlinear equalizers based on both the 64 QAM experimental platform and the QPSK numerical platform. The global convolution operation of the proposed CvGNN is more suitable for the calculation process of perturbation coefficients, and the global receptive field can also be more effective at extracting effective information from perturbation feature maps. The introduction of CvCNN can directly focus on the complex-valued perturbation feature maps themselves without separately processing the real and imaginary parts, which is more in line with the waveform-dependent physical characteristics of optical signals. Based on the experimental platform, compared with the real-valued neural network with small convolutional kernel (RvCNNC), the proposed CvGNNC improves the Q-factor by ∼2.95 dB at the optimal transmission power, while reducing the time complexity by ∼44.7%.