2023
DOI: 10.1002/adfm.202308096
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Intriguing Room Temperature Phosphorescence in Crystalline Porous Organic Frameworks

Yu‐Qi Zhu,
Xing‐Huo Wang,
Ming‐Xue Wu

Abstract: Organic room temperature phosphorescence (RTP) materials have become a hot topic in the field of luminescence wherein the crystalline porous organic frameworks (metal–organic frameworks (MOFs), hydrogen‐bonded organic frameworks (HOFs), covalent organic frameworks (COFs))‐based RTP materials are receiving considerable attention. Beyond all doubt, crystalline porous organic frameworks‐based RTP materials perfectly integrate the advantages of crystalline porous organic frameworks and RTP materials. This review p… Show more

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Cited by 24 publications
(4 citation statements)
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“…Essentially, the design for RTP materials revolves around two crucial factors: firstly, the facilitation of the intersystem crossing (ISC) process to achieve the triplet excited state; secondly, the effective mitigation of nonradiative transitions in the triplet state excitons. 110…”
Section: Applicationsmentioning
confidence: 99%
“…Essentially, the design for RTP materials revolves around two crucial factors: firstly, the facilitation of the intersystem crossing (ISC) process to achieve the triplet excited state; secondly, the effective mitigation of nonradiative transitions in the triplet state excitons. 110…”
Section: Applicationsmentioning
confidence: 99%
“…Up to now, despite the significant progresses of acquiring colorful room-temperature phosphorescence (RTP) in organic phosphors, where the cocrystallization, , host–guest coassembly, , molecular polymerization, , supramolecular polymerization, , and metal–organic framework (MOF)/covalent organic framework (COF) incarceration have been developed, the structural breakthroughs and mechanistic unveilings of colorfully emissive crystals with hybrid singlet, doublet, triplet excited states, and noninvasive stimulate manipulation are still an intriguing but challenging topic in the field of single-component organic room-temperature phosphorescence (ORTP), not to mention integrating color-tunable CPPL (Figure b) …”
Section: Introductionmentioning
confidence: 99%
“…The developed RTP system is expected to be widely used in optical information encryption and other fields. 41–50…”
Section: Introductionmentioning
confidence: 99%