Investigating spatial and temporal trend of groundwater quality in relation to water balance in 2007–2017: a case study of Chaharmahal va Bakhtiari Province, Iran

Abstract

The extensive exploitation of water resources in Chaharmahal va Bakhtiari province has led to a destructive impact on the water balance and quality of the region. In order to evaluate water quality of the study area, water quality parameters from 132 wells were analyzed to prepare spatial distribution maps of the IRWQI index. To analyze spatial and temporal rainfall anomalies, the SPI index was spatially interpolated using the ordinary Kriging method. Principal component analysis was used to investigate the relationship between water quality parameters. The suitability of data for PCA was evaluated by the Kaiser–Meyer–Olkin and Bartlett tests. Additionally, water balance components of the study area, including surface runoff and ground water, were simulated using the WetSpass-M model. According to the results of the IRWQI index, 54 wells, mostly located in built-up and agricultural lands, had poor quality․ Investigation of the average groundwater quality during the years 2007 to 2017 shows that the trend of groundwater quality decreased. Comparison of drought and water quality maps showed similar patterns so that in areas with extreme drought, water quality was bad. The highest and lowest recorded concentrations for nitrates were related to built-up and rangeland lands with concentrations of 35 and 21 mg/l, respectively. Comparison among land use classes showed that in the rangelands, groundwater quality was better and nitrate level was lower compared to agricultural and built-up areas. Overall, the results of this study show that water quality can be affected by land use types and water balance components.