Investigation of the local environment and the superhyperfine interactions of an Fe3+ center in α-LiIO3 by the method of radiofrequency discrete saturation

The models of two types of paramagnetic centres in manganese-doped LiIO, are determined by means of the radiofrequency discrete saturation method (RFDS) and ENDOR, which measure the superhyperfine interactions of the centres with the neighbouring ?Li nuclei. Manganese is arranged a t lithium sites and charge compensation results from a vacancy a t a lithium site. The measured quadrupolar splitting parameters of the 'Li nuclei are calculated with good agreement in point charge approximation on the basis of the models determined. Die Nodelle Ton zwei Srten paramagnetischer Zentren in mangandotiertem LiIO, werden mit derNethode' der diskreten Radiofrequenzskttigung (RFDS) und ENDOR bestimmt. Diese Xethoden messen die Superhyperfeinwechselwirkung der Zentren mit den benachbsrten 'Li-Kernen. Xangan ist auf Lithiumpltltzen angeordnet. Die Ladungskompensation erfolgt durch eine Lithiumvakanz. Die gemessenen Quadrupolaufspaltungsparameter der 'Li-Kerne werden theoretisch in Pnnktladungsnaherung suf der Basis der ermittelten Modelle mit guter ubereinstimmung berechnet.

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Investigation of Superhyperfine Interactions of Mn²⁺ in α‐LiIO₃ and Evaluation of Lithium Quadrupolar Interactions

Daraselia

Bräer

1982

Physica Status Solidi (b)

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Investigation of the local environment and the superhyperfine interactions of an Fe3+ center in α-LiIO3 by the method of radiofrequency discrete saturation

Cited by 1 publication

References 7 publications

Investigation of Superhyperfine Interactions of Mn²⁺ in α‐LiIO₃ and Evaluation of Lithium Quadrupolar Interactions

Investigation of Superhyperfine Interactions of Mn²⁺ in α‐LiIO₃ and Evaluation of Lithium Quadrupolar Interactions

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Investigation of the local environment and the superhyperfine interactions of an Fe3+ center in α-LiIO3 by the method of radiofrequency discrete saturation

Cited by 1 publication

References 7 publications

Investigation of Superhyperfine Interactions of Mn2+ in α‐LiIO3 and Evaluation of Lithium Quadrupolar Interactions

Investigation of Superhyperfine Interactions of Mn2+ in α‐LiIO3 and Evaluation of Lithium Quadrupolar Interactions

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Investigation of Superhyperfine Interactions of Mn²⁺ in α‐LiIO₃ and Evaluation of Lithium Quadrupolar Interactions

Investigation of Superhyperfine Interactions of Mn²⁺ in α‐LiIO₃ and Evaluation of Lithium Quadrupolar Interactions