Ionic conductance behavior of polymeric gel electrolyte containing ionic liquid mixed with magnesium salt

Translational dynamics of ionic liquid imidazolium cations at solid/liquid interface in gel polymer electrolyte

“…In situ photopolymerization is especially attractive method of preparation of novel solid polymer electrolytes with ionic conductivity suitable for practical applications (above 1 mS/cm) [16][17][18][19][20]. This technique involves photocuring of a homogeneous mixture composed of a monomer (the polymer matrix precursor) and an IL, and enables preparation of a gel polymer electrolyte (GPE) in a few minutes.…”

Experimental investigations of an ionic-liquid-based, magnesium ion conducting, polymer gel electrolyte

“…They are room temperature molten salts that typically consist of bulky, asymmetric organic cations and inorganic anions, and possess many attractive properties such as non-volatility, non-flammability, excellent thermal stability, high ionic conductivity, and wider electrochemical windows [18][19][20][21][22][23]. More recently, ionic-liquid-based polymer gel electrolytes have also been examined for application as promising electrolytes in batteries, supercapacitors and fuel cells [18,19,[24][25][26][27][28].…”

Spectroscopic Investigation of Composite Polymeric and Monocrystalline Systems with Ionic Conductivity

“…The solution (11) gives new C mj and F ij until C mj is the same. This calculation is carried out for the valence electrons with the minimal basis and a considerable part of Coulomb integrals is neglected (13). In this work, the method MNDO/d is used to calculate local minimal energies during the interaction of Li atoms with the polymeric chain of polyethylene oxide.…”

“…The third class of polymeric electrolytes, which are polymers with lithium salt (e.g., LiCF 3 SO 3 ), is least studied. Their conductivity is controlled by the change of the polymeric matrix, impurity salt and temperature [11][12][13][14][15][16]. Polyethylene oxide (PEO) as a simple polyether can be chosen as the polymeric matrix due to its low molecular weight and an ease of solubility in water.…”