2024
DOI: 10.1021/prechem.4c00003
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Kinetic Insights into Boron-Based Materials Catalyzed Oxidative Dehydrogenation of Light Alkanes

Hao Tian,
Bingjun Xu

Abstract: High selectivity toward alkenes in oxidative dehydrogenation (ODH) of light alkanes makes boron-based materials promising catalysts. However, many key mechanistic aspects are still debated due to the challenge of capturing fleeting reaction intermediates. Kinetic analysis, including determining reaction orders and activation energy, could be informative for reactions involving radical intermediates but has not been extensively exploited. This Review summarizes the current understanding of the apparent alkane r… Show more

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