2015
DOI: 10.5796/electrochemistry.83.807
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Kinetic Study of Oxygen Reduction Reaction in Acid Solution Using Titanium Oxide-based Catalysts Prepared from Oxy-titanium Tetra-pyrazino-porphyrazine

Abstract: Oxide-based electrocatalysts were investigated as non-platinum cathodes for the oxygen reduction reaction (ORR). Recently, we found that titanium oxide-based compounds produced from oxy-titanium tetra-pyrazino-porphyrazine via oxidation under low oxygen partial pressure exhibited high ORR activity [T. Hayashi et al., ECS Trans., 64(3), 247 (2014)]. However, the mechanism by which the ORR proceeds in the presence of titanium oxide-based catalysts has not yet been analyzed in detail. In this study, the ORR mecha… Show more

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Cited by 7 publications
(2 citation statements)
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“…The catalysts were synthesized by the thermal decomposition of oxytitanium tetrapyrazinoporphyrazine (TiOTPPz) on multiwalled carbon nanotubes as reported previously. 9,14 In brief, TiOTPPz was mixed with carbon nanotubes, (i) heated up to 900 °C in Ar, (ii) retained at the temperature in Ar containing 2% H 2 and 0.05% O 2 , where equilibrium O 2 partial is 1.3 × 10 −19 atm (retention time = 0, 0.5, 1, 3, 5, and 10 h), and then (iii) cooled down to room temperature. To investigate the contribution of the carbon materials to the catalytic reactions, the samples without oxides were prepared by removing the oxides with hydrofluoric acid.…”
Section: ■ Introductionmentioning
confidence: 99%
“…The catalysts were synthesized by the thermal decomposition of oxytitanium tetrapyrazinoporphyrazine (TiOTPPz) on multiwalled carbon nanotubes as reported previously. 9,14 In brief, TiOTPPz was mixed with carbon nanotubes, (i) heated up to 900 °C in Ar, (ii) retained at the temperature in Ar containing 2% H 2 and 0.05% O 2 , where equilibrium O 2 partial is 1.3 × 10 −19 atm (retention time = 0, 0.5, 1, 3, 5, and 10 h), and then (iii) cooled down to room temperature. To investigate the contribution of the carbon materials to the catalytic reactions, the samples without oxides were prepared by removing the oxides with hydrofluoric acid.…”
Section: ■ Introductionmentioning
confidence: 99%
“…Some of the possible alternatives can be catalysts based on transition metal in nitrogen doped graphitic cathodes, [11] oxides and oxynitrides of transition metals e. g. tantalum, [12,13] zirconium oxide based catalysts with multiwalled carbon nanotube (MWCNTs) support [14] and niobium‐titanium complex oxides, [15] among others. Exploring the ORR mechanisms on various catalyst surface, and consequently the active sites, using Density Functional Theory (DFT), helps us gain fundamental understanding regarding the same.…”
Section: Introductionmentioning
confidence: 99%