La-Doped Sm2Zr2O7/PU-Coated Leather Composites with Enhanced Mechanical Properties and Highly Efficient Photocatalytic Performance

Abstract

Flexible La-doped Sm2Zr2O7/polyurethane (PU) coated leather composites were synthesized using a one-step hydrothermal method, with highly efficient photocatalytic degradation properties by coating the La-doped Sm2Zr2O7/PU emulsion onto the leather and drying it. The phase composition and optical properties of the as-prepared photocatalytic material were systematically characterized. The result revealed that La was doped in Sm2Zr2O7 successfully, and the prepared samples still possessed pyrochlore structure. The absorption edge of the prepared samples exhibited a red-shift with the increase in La doping, indicating that La doping could broaden the absorbance range of the La-doped Sm2Zr2O7 materials. The catalytic performance of La-doped Sm2Zr2O7/PU composite emulsion coating on the photocatalytic performance of leather was studied with Congo red solution as the target pollutant. The results showed that the best photocatalytic property was found in the 5% La-doped Sm2Zr2O7 nanomaterial at a concentration of 3 g/L. The resulting 5% La-doped Sm2Zr2O7 nanomaterial exhibited a high specific surface area of 73.5 m2/g. After 40 min of irradiation by a 450 W xenon lamp, the degradation rate of Congo red reached 93%. Moreover, after surface coating, the La-doped Sm2Zr2O7/PU coated leather composites showed obviously improved mechanical properties, as the tensile strength of La-doped Sm2Zr2O7/PU coated leather composites increased from 6.3 to 8.4 MPa. The as-prepared La-doped Sm2Zr2O7/PU coated leather composites with enhanced mechanical properties and highly efficient photocatalytic performance hold promising applications in the treatment of indoor volatile organic compounds.

Polyurethane Composites Recycling with Styrene–Acrylonitrile and Calcium Carbonate Recovery

“…For the synthesis of polyurethane foams, two main reactants, polyol and isocyanate, are employed, and additives like catalysts, surfactants, antioxidants and fillers are incorporated in order to obtain products with suitable properties for the market demand [ 7 , 8 , 9 , 10 ]. In the case of flexible polyurethane foams, fillers, such as calcium carbonate, are often used to obtain better firmness, resistance to impact, less flammability, less fragility and even a smoother and durable surface [ 11 , 12 ].…”