This paper intends to apply the Intelligent Wireless Sensor Network (IWSN) to the archaeological excavation site and make the dynamic site of archaeological excavation can be monitored intelligently in real-time. This paper firstly discusses the structure and function of Wireless Sensor Network (WSN). Secondly, according to the problem of limited dynamic monitoring of WSN, an IWSN is established. The dynamic environmental monitoring of archaeological excavation sites is achieved by using Geographic Information System (GIS) and remote sensing technology combined with IWSN. Finally, this paper analyses the environmental monitoring results of the archaeological excavation site, the dynamic environmental monitoring location of the archaeological excavation site of the IWSN, and the simulation results of the Intelligent Wireless Sensor Network-Geographic Information System (IWSN-GIS) in the dynamic environmental monitoring of the archaeological excavation site. The results show that the Inverse Distance to a Power (IDP) algorithm in temperature and humidity monitoring data on the overall downward trend, the algorithm performance is relatively stable, and the algorithm performance is better than the other two algorithms. The monitoring performance of IWSN-GIS system is better than that of IWSN system. It shows that with the increase in the communication distance of sensor nodes, the relative error of different monitoring systems for the dynamic monitoring position of the archaeological excavation site is decreasing. IWSN-GIS can monitor the environment before, during, and after the archaeological site. This paper realizes the intelligent, scientific, and technological archaeology of archaeological excavation through IWSN, GIS, and remote sensing image technology, and provides technical support for digital archaeology in archaeological research.