“…There have been numerous experimental studies on the interaction of U VI aq with layersilicate clays (Goldsztaub and Wey, 1955;Giblin, 1980;Borovec, 1981;Giblin et al, 1981;Tsunashima et al, 1981;Ames et al, 1982Ames et al, , 1983aAndersson et al, 1982;ChisholmBrause et al, 1992ChisholmBrause et al, , 1994Dent et al, 1992;McKinley and Sholtis, 1993, and references therein;Vandergraaf et al, 1993, see references therein;Hudson et al, 1994;Morris et al, 1994;Ticknor, 1994;McKinley et al, 1995;Ticknor et al, 1996;Giaquinta et al, 1997;Turner et al, 1996;Morris et al, 1997;Pabalan and Turner, 1997;Redden et al, 1997;Akcay, 1998;Pabalan et al, 1998;Thompson et al, 1998;Nero et al, 1999;Syed, 1999). None of these studies, however, addressed heterogeneous reduction of U VI by structural Fe II .…”