This paper is concerned with the study of the random variable Kn denoting the number of distinct elements in a random sample (X1, . . . , Xn) of exchangeable random variables driven by the two parameter Poisson-Dirichlet distribution, PD(α, θ). For α ∈ (0, 1), Theorem 3.8 in [23] shows that Kn n α a.s.−→ S α,θ as n → +∞. Here, S α,θ is a random variable distributed according to the so-called scaled Mittag-Leffler distribution. Our main result states thatholds with an explicit constant C(α, θ). The key ingredients of the proof are a novel probabilistic representation of Kn as compound distribution and new, refined versions of certain quantitative bounds for the Poisson approximation and the compound Poisson distribution. Finally, we present the following application in the context of Bayesian nonparametric inference for species sampling problems: given an initial (observable) random sample (X1, . . . , Xn) from the population, estimate of the number K (n) m of hitherto unseen species that would be observed in m additional (unobservable) samples. In the approach proposed in [8], (X1, . . . , Xn) is a random sample from PD(α, θ) featuring Kn = j ≤ n species (blocks), for which there holds K (n) m m α | (X1, . . . , Xn) a.s. −→ S α,θ (n, j) as m → +∞, where S α,θ (n, j) is related to S α,θ+n . Thus, we combine the previous main result with a new Berry-Esseen bound for de Finetti's theorem recently obtained in [6], to obtain another Berry-Esseen theorem for the convergence of the distribution of K (n) m m α | (X1, . . . , Xn).