1989
DOI: 10.1016/s0003-2670(00)81982-0
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Laser raman spectroscopy. Analytical applications

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Cited by 36 publications
(49 citation statements)
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“…An additional signal, which appears at a shoulder, at about 2876 cm -1 was observed which was assigned to stretching vibrations in CH 2 groups bonded to an unsaturated carbon atom (-CH 2 -CH=CH-) present in unsaturated fatty acids. The bonding of an unsaturated carbon atom to a CH 2 group shifts the absorption band for the C-H bond in the methylene group (Baranska, et al, 1987). A sixth signal was observed above 3000 cm -1 due to stretching vibrations of the C-H bond of =C-H groups in fatty acid chains.…”
Section: Raman Spectramentioning
confidence: 97%
“…An additional signal, which appears at a shoulder, at about 2876 cm -1 was observed which was assigned to stretching vibrations in CH 2 groups bonded to an unsaturated carbon atom (-CH 2 -CH=CH-) present in unsaturated fatty acids. The bonding of an unsaturated carbon atom to a CH 2 group shifts the absorption band for the C-H bond in the methylene group (Baranska, et al, 1987). A sixth signal was observed above 3000 cm -1 due to stretching vibrations of the C-H bond of =C-H groups in fatty acid chains.…”
Section: Raman Spectramentioning
confidence: 97%
“…Usually the symmetric vibration is stronger than antisymmetric one in the Raman spectra and the contrary holds in infrared [14,15]. This could be due to the electron withdrawing substituent adjacent to the nitro group which tends to increase the frequency of asymmetric vibration and decrease that of the symmetric vibration.…”
Section: Wwwcrt-journalorgmentioning
confidence: 99%
“…This is called Stokes scattering (vR(StJ) (Diem 1993;Grasseli & Bulkin 1991;Schrader 1996). uR(StJ in view of the difference of population of the ground excited electronic states in a set of molecules at room temperature (Baranska, Labudzinska & Terpinski 1987). The Raman spectra presented in this chapter concern only the Raman-Stokes scattering bands.…”
Section: Raman Spectroscopymentioning
confidence: 99%
“…• inter-atomic distances • spatial arrangement groups • Fermi resonance • physical state of the sample • polarity of the environment • formation of hydrogen bonds • inductive, mesomeric, and field effects of neighboring groups In this way, the difference in the force constant, for example, explains that the stretching frequency of double bonds is higher than that of single bonds (Baranska, Labudzinska & Terpinski 1987;Diem 1993;Grasseli & Bulkin, 1991).…”
Section: Band Position and Intensitymentioning
confidence: 99%
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