Ligand-directed copper(І) azide coordination polymers bridged by N-donor ligands with different lengths: azide exhibits a rare μ−1, 1, 3, 3 bridging mode

Fan, Guifen; Chen, San Ping; Gao, Shengli

doi:10.1007/s11224-007-9223-5

Cited by 9 publications

(2 citation statements)

References 37 publications

(43 reference statements)

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“…Studying the influence of the co-ligands on the bridging modes of the azido groups may help us better understand and control the topologies of the azido-bridged complexes. Moreover, the l 1,1,3 -bridging mode of the azido groups in the copper(II) complexes is very rare; to date, there were only a few other l 1,1,3 -azido-bridged copper(II) complexes that have been reported [7][8][9][10][11][12][13][14]. Thus, more work needs to be done to design and construct new polynuclear complexes with l 1,1,3 -azido bridges.…”

Section: Introductionmentioning

confidence: 99%

Tuning the bridging modes of Cu-azido complexes with Schiff bases by varying the terminal groups

Zhang

Zhou

Wang

et al. 2010

Transition Met Chem

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Section: Introductionmentioning

confidence: 99%

Tuning the bridging modes of Cu-azido complexes with Schiff bases by varying the terminal groups

Zhang

Zhou

Wang

et al. 2010

Transition Met Chem

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“…The last in this issue is a communication by Fan et al [353] who report on the hydrothermal syntheses and crystal structures of three copper(I) azide coordination polymers, [Cu 2 (bpe)(N 3 ) 2 ] n , [Cu 2 (bpy)(N 3 ) 2 ] n and [Cu 4 (py)(N 3 ) 4 ] n (bpe = trans-1,2-di-(4-pyridyl)ethene, bpy = 4,4 0 -bipyridine, py = pyrazine). It was shown that the structures of the complexes changed from 2D to 3D networks upon reducing the lengths of the bridging ligands.…”

Section: Issuementioning

confidence: 96%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

Ponikvar

Liebman

2008

Struct Chem

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In this study, we relate the contents of the journal Structural Chemistry for the calendar year 2007 and thermochemistry. The year's articles were briefly summarized and a thermochemical comment written to supplement them. Frequently questions were asked and future research was suggested.Keywords Structural Chemistry Á Thermochemistry Á Thermodynamics Á Enthalpy of formation Á Enthalpy of phase change Á Enthalpy of reaction As practiced disciplines, structural chemistry and thermochemistry are very often unrelated. In this study, these disciplines are linked as relations are explicitly made using the contents of the journal Structural Chemistry (Vol. 18) for the calendar year 2007 as a scaffold for our analysis, for our selected articles in the discipline of structural chemistry. These studies have been reviewed by us, where we give them a thermochemical flavor. While this commentary is most generally written in terms of brief summaries of literature papers involving enthalpies of formation and/or reaction, not uncommonly we raise questions and even suggest possible future research. We are not, however, going to give a thermochemical slant on book reviews, honorary dedications, and obituaries although these works will be cited in our text.As such, this article is a sequel to our earlier related reviews of Structural Chemistry for the calendar years 2000 through 2004 [1-5]. Reviews for 2005 and 2006 are currently being prepared. Issue 1In the first article in the first issue of Structural Chemistry for 2007, Hargittai [6] asserted that while research is currently usually carried out in big groups, the most important ideas, observations and discoveries still belong to individuals who have to bring down dogmas or open entirely new areas in science. This may bring solace to the thermochemical community in which research groups are generally small, and the number of new practitioners sadly few.In the past decade, the crystal engineering of multidimensional arrays and networks containing metal ions has achieved considerable progress because of the increased interest in the potential utility of these compounds as zeolite-like materials [7-11], catalysts [12], or magnetic materials [13][14][15]. The thermochemistry of these species is complicated by their inherent complexity: however, estimation approaches of their key thermochemical quantities are increasingly reliable [16]. In the second article of this issue, by Wang et al. [17], the versatility of malonate dianion as a ligand for the construction of extended networks with different topologies dependent on the coordination geometry of the metal ion was discussed. The synthesis and structure of a novel malonate-bridged copper(II) compound in which copper(II) ions have two different coordination environments in a novel three-dimensional (3D) network was described. Metal malonates have been studied from a

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[Cu2(μ-Me2N–ba)2bn)I]n, 1D coordination polymer of copper(I) iodide: synthesis, characterization, and crystal structure

et al. 2013

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Ligand-directed copper(І) azide coordination polymers bridged by N-donor ligands with different lengths: azide exhibits a rare μ−1, 1, 3, 3 bridging mode

Cited by 9 publications

References 37 publications

Tuning the bridging modes of Cu-azido complexes with Schiff bases by varying the terminal groups

Tuning the bridging modes of Cu-azido complexes with Schiff bases by varying the terminal groups

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

[Cu2(μ-Me2N–ba)2bn)I]n, 1D coordination polymer of copper(I) iodide: synthesis, characterization, and crystal structure

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