2024
DOI: 10.1002/admi.202400411
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Ligand Substituent Effects on the Electronic Properties of Lindqvist‐Type Polyoxometalate Multi‐Level‐Switches in the Gas Phase, Solution and on Surfaces

Fangshun Yang,
Givi Kalandia,
Marco Moors
et al.

Abstract: Although the intrinsic electronic properties of polyoxometalates (POMs) can be greatly influenced by modifying them with organic substituents, their resistive switching behavior on surfaces dependent on the organic substituents remains largely unexplored. In this work, we assessed the importance of electron‐withdrawing and electron‐donating ligand substituents on the material properties of a series of hybrid Lindqvist‐type hexavanadates TBA2[V6O13((OCH2)3CCH2OH)2] (TBA2V6‐OH), TBA2[V6O13((OCH2)3CMe)2] (TBA2V6‐… Show more

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