Lignocellulosic nanomaterials production from wheat straw via peracetic acid pretreatment and their application in plastic composites

Pascoli, Danielle Uchimura; Dichiara, Anthony B.; Roumeli, Eleftheria; Gustafson, Rick; Bura, Renata

doi:10.1016/j.carbpol.2022.119857

Cited by 20 publications

(14 citation statements)

References 55 publications

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“…When compared to nanofibers produced via harsher reactions such as TEMPO-mediated oxidation (usually around 1000 µmol g −1 ), the CD values reported in this work for CS, RCG, and IH (110–344 µmol g −1 ) are relatively lower due to the milder oxidation reaction that occurs during PAA pretreatment, as previously reported by our group [ 16 ]. Studies reported that CD largely improves nanofibrillation by promoting Coulombic repulsion forces between the fibers, hence the high efficacy of TEMPO oxidation in producing very small nanofibers [ 53 ].…”

Section: Resultssupporting

confidence: 75%

“…The three biomass feedstocks underwent alkaline peroxide pulping following the same procedure previously reported by our group for the conversion of wheat straw [ 16 ]. After pulping, the samples were vacuum filtered, and the pulps were extensively washed with deionized (DI) water.…”

Section: Methodsmentioning

confidence: 99%

“…The refined pulps were submitted to peracetic acid (PAA) pretreatment based on the procedure reported by [ 16 ] with some modifications. First, the refined pulps were mixed with PAA solution (2 wt.%) at pH 4.8 in a plastic bottle to achieve 5% pulp consistency, and the reaction was carried out at 85 °C for 45 min in a water bath.…”

Section: Methodsmentioning

confidence: 99%

“…In a previous study, our research group established a conversion process to produce lignocellulosic nanofibers from wheat straw biomass, a highly available food crop residue in the United States. The conversion process consists of mild alkaline peroxide pulping (for delignification) and peracetic acid pretreatment (for carbohydrate oxidation) followed by mechanical treatments (for fibrillation), generating unique lignocellulosic nanofibers with excellent bioplastic reinforcement properties [ 16 ]. The previous research demonstrated a promising route to producing inexpensive lignocellulosic nanofibers directly from waste feedstocks, motivating a further techno-economic analysis and life cycle assessment of the lignocellulosic nanofiber product.…”

Section: Introductionmentioning

confidence: 99%

“…The three biomass feedstocks selected in this study (CS, RCG, and IH) have great potential for high-value biomaterial applications, either due to their high availability, invasive nature, low-value market, or low water and nutrient requirements. In this work, they are used to produce high-value lignocellulosic nanofibers via the conversion process previously described by our research group [ 16 ]. The present work aims to (1) assess the robustness of the conversion process by using agricultural waste feedstocks from various plant species and (2) elucidate how the specific chemical and physical characteristics of the biomass feedstocks affect the properties of the final products.…”

Section: Introductionmentioning

confidence: 99%

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A Robust Process to Produce Lignocellulosic Nanofibers from Corn Stover, Reed Canary Grass, and Industrial Hemp

et al. 2023

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The use of agricultural waste biomass for nanocellulose production has gained interest due to its environmental and economic benefits compared to conventional bleached pulp feedstock. However, there is still a need to establish robust process technologies that can accommodate the variability of waste feedstocks and to understand the effects of feedstock characteristics on the final nanofiber properties. Here, lignocellulosic nanofibers with unique properties are produced from various waste biomass based on a simple and low-cost process using mild operating conditions. The process robustness is demonstrated by diversifying the feedstock, ranging from food crop waste (corn stover) to invasive grass species (reed canary grass) and industrial lignocellulosic residues (industrial hemp). This comprehensive study provides a thorough examination of the influence of the feedstocks’ physico-chemical characteristics on the conversion treatment, including process yield, degree of delignification, effectiveness of nanofibrillation, fiber morphology, surface charge, and density. Results show that nanofibers have been successfully produced from all feedstocks, with minor to no adjustments to process conditions. This work provides a framework for future studies to engineer nanocellulose with specific properties by taking advantage of biomass feedstocks’ intrinsic characteristics to enable versatile applications.

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Section: Resultssupporting

confidence: 75%

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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A Robust Process to Produce Lignocellulosic Nanofibers from Corn Stover, Reed Canary Grass, and Industrial Hemp

et al. 2023

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Characterization of holocellulose extracted from agricultural and food processing byproducts via ecofriendly delignification pulping process

Lin,

Jung,

Zhao

2024

J of Applied Polymer Sci

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This study investigated an ecofriendly peracetic acid delignification process to extract holocellulose from various fiber rich plant‐based byproducts (coconut palm spathe/leaf, apple pulp, wine grape pomace, hazelnut shell, and hemp fiber/hurd), and evaluated their physicochemical, morphological, and thermophysical properties in comparison with commercial cellulose nanofibers produced from wood. Holocellulose from coconut palm spathe has long fiber (~846.7 μm), whereas that from wine grape pomace and hazelnut shell exhibits a cylinder shape of particles with short fiber length (~123.8 and ~ 71.1 μm, respectively). Biofilms cast from apple pulp and hemp fiber holocellulose have higher degradation temperature (361 and 358°C, respectively) than biofilms from other materials, thus more thermally stable. All biofilms demonstrate high UV absorbance, and the biofilm cast from apple pulp holocellulose is transparent with smooth surface. Fourier‐transform infrared spectroscopy analysis confirms the presence of cellulose and hemicellulose as the main components in the biofilms, along with traces of residual lignin that remained after the extraction process. This study demonstrates that holocellulose with varied cellulose morphology and polymeric characteristics could be extracted depending on the type of byproducts and be employed to produce sustainable packaging materials.

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Hierarchical biopolymer‐based materials and composites

Fredricks

Jimenez

Grandgeorge

et al. 2023

Journal of Polymer Science

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The mass production and disposal of non‐degradable fossil‐based plastics is responsible for alarming environmental and social issues when not managed responsibly. Towards manufacturing environmentally‐friendly materials, biopolymers, that is, polymers synthesized by living organisms, emerge as promising sustainable alternatives as they combine attractive mechanical properties, compostability, and renewable sourcing. In this review, we analyze the structural and mechanical properties of three of the most studied biopolymer classes: cellulose, chitin, and protein beta‐sheet structures. We first discuss the hierarchical structure of the biopolymers and how their rich interaction networks induce appealing mechanical properties. Then, we review different fabrication and processing methods to translate these attractive properties into macroscopic materials and composites. Finally, we discuss a nascent approach, which leverages the direct use of microorganisms, in the form of intact cells, tissues or dissociated biological matter (biomatter), as meso‐scale material building blocks. These non‐ or little pre‐processed biomatter building blocks are composed of the biopolymer structural elements (molecular‐nano scale), but also inherit the higher‐scale hierarchical characteristics. Processing‐structure–property relationships for biomatter‐based materials are discussed, emphasizing on the role of hierarchical arrangement, processing‐induced transformations, and intermolecular bonding, on the macroscopic mechanical properties. Finally, we present a perspective on the role of biopolymers in a circular economy.

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Lignocellulosic nanomaterials production from wheat straw via peracetic acid pretreatment and their application in plastic composites

Cited by 20 publications

References 55 publications

A Robust Process to Produce Lignocellulosic Nanofibers from Corn Stover, Reed Canary Grass, and Industrial Hemp

A Robust Process to Produce Lignocellulosic Nanofibers from Corn Stover, Reed Canary Grass, and Industrial Hemp

Characterization of holocellulose extracted from agricultural and food processing byproducts via ecofriendly delignification pulping process

Hierarchical biopolymer‐based materials and composites

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