Linked macrocyclic systems. Interaction of copper(I) with tris-ring N2S2-donor macrocycles and their single-ring analogues

Macrocyclic coordination chemistry

“…105 The copper(I) complex of the tris-macrocyclic system containing three linked N 2 S 2 macrocycles L 75 was synthesised, demonstrating a 3:1 metal to ligand ratio as was expected. 106 The X-ray crystal structure of the single ring analogue was solved showing a distorted tetrahedral geometry around the copper(I) centre.…”