Linking molybdenum or tungsten with platinum. The synthesis and molecular structure of PtMo(.mu.-Ph2Ppy)2(.mu.-CO)(CO)2Cl2 [Ph2Ppy = 2-(diphenylphosphino)pyridine]

Head-to-head and head-to-tail isomers of binuclear complexes of platinum(I) and palladium(I) involving 2-(diphenylphosphino)pyridine as a bridging ligand

“…The lines in the spectrum are expected to be narrower than the lines observed for the HT complex since the phosphorus atoms are trans to phosphorus atoms rather than quadrupolar nitrogen atoms. In fact, the natural line width of the HH isomer is only 20 Hz, while it is 80 Hz for the HT isomer.…”

Organometallic complexes with metal-metal bonds. 19. Comparison of two strategies towards the syntheses of platinum mixed-metal clusters. Reactivity of linear M-Pt-M and Mn-Pt-Mn complexes. X-ray crystal structures of Pt2M2(.eta.5-C5H5)2(.mu.3-CO)2(.mu.-CO)4(PEt3)2 with M = Cr, Mo, and W

“…The , 13C{*H), and 31 ( ) NMR spectra were recorded at 90.00, 200.13, or 250.00; 22. 63 B. Synthesis. The phosphine ligands PEt3, P-/i-Bu3, and PPh3 were used as received (Fluka commercial grade), except PMe3, which was prepared according to the procedure described in the literature42 (Me = CH3; Et = C2H5; Bu = C4H9; Ph = C6H5).…”

Synthesis and structure of new palladium complexes with the ligand 2-(diphenylphosphino)-1-methylimidazole: Evidence of hemilability

“…We agree with Cavell et al that the most reasonable structure for this derivative is that with two HT dpim bridges. A trans HT disposition of the ligands has also been observed in homodinuclear systems and in the majority of the heterodinuclear derivatives with the PPh 2 py ligand [16,17]. They proposed that the difference between the major and minor isomers concerns the relative disposition of the chloride and methyl ligands on the two metal centres (''cisoid'' or ''transoid'').…”