“…Our results were used to quantify the effect of highly reactive Al and Fe minerals, led by the allophane (41.38%) and ferrihydrite composition (25.68%), which were consistent with studies by a selective extraction method (Yu et al, 2012;Zhang et al, 2013a;Wen et al, 2014). This result could be because with a shift in microbial metabolism and enzyme production, the meta-stable highly reactive Al and Fe minerals (e.g., allophane and ferrihydrite) could form stable organo-mineral bonds through anion and inner-sphere ligand-exchange reactions, thus being well-suited to physically protect the geometries (Rasmussen et al, 2006;Schmidt et al, 2011;Xie et al, 2014).…”