2008
DOI: 10.1016/j.vibspec.2007.12.014
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Low-frequency vibrational excitations in a niobium–phosphate glass for Raman gain applications

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Cited by 12 publications
(13 citation statements)
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“…Schulte et al found that binary niobium-phosphate glasses show manifest low-frequency enhancement of the vibrational density of states. This suggests a significant gain profile for application in Raman amplifiers as well as providing an additional mechanism for Raman gain [4]. Modification of properties and structure of Nb-phosphate glasses has been extensively studied by the addition of several different oxides, such as by lithium oxide [5], iron oxide and lithium oxide [6], calcium oxide and lithium oxide [7], and sodium oxide [8].…”
Section: Introductionmentioning
confidence: 99%
“…Schulte et al found that binary niobium-phosphate glasses show manifest low-frequency enhancement of the vibrational density of states. This suggests a significant gain profile for application in Raman amplifiers as well as providing an additional mechanism for Raman gain [4]. Modification of properties and structure of Nb-phosphate glasses has been extensively studied by the addition of several different oxides, such as by lithium oxide [5], iron oxide and lithium oxide [6], calcium oxide and lithium oxide [7], and sodium oxide [8].…”
Section: Introductionmentioning
confidence: 99%
“…La muestra de N b 2 O 5 · 3H 2 O puso a la vista una señal intensa y amplia cerca de 650 cm −1 que fue asignada a los estiramientos simétricos de los poliedros del enlace N b − O [39], ligeramente distorsionados. La banda alrededor de los 230 cm −1 aparece debido al modo de flexión del enlace Nb-O-Nb [39], también podrían estar relacionadas con los enlaces Nb-O-Nb, estiramientos simétricos Nb-O del N b 2 O 5 anhidro y estiramientos simétricos Nb=O presentes en la superficie tanto del oxido anhidro como el hidratado [40].…”
Section: Caracterización De Los Catalizadoresunclassified
“…La señal amplia entre los 1200 cm −1 y 1800 cm −1 se debe a un modo activo de la fase anatasa [43]. Puede apreciarse que el patrón de bandas correspondiente a las vibraciones M-O-M (M=metal) es diferente para ambos óxidos debido a la naturaleza del metal, el niobio posee un radio más grande que el titanio y permite acomodar especies poliédricas del enlace Nb-O [39] en su estructura, influyendo así en la apariencia e intensidad de las bandas M-O-M, con respecto al T iO 2 degussa P-25.…”
Section: Caracterización De Los Catalizadoresunclassified
“…[18]. For neutron scattering experiments the samples powder form was filled in Nb double-cylinders with 0.1 mm wall thickness.…”
Section: Inelastic Neutron and Raman Scatteringmentioning
confidence: 99%
“…The spontaneous Raman spectra were measured in a vv geometry using 514.53 nm excitation and a double monochromator equipped with a photon counting system [18]. In Fig.…”
Section: Inelastic Neutron and Raman Scatteringmentioning
confidence: 99%