Borca, C.N.; Adenwalla, Shireen; Bune, A.V.; Ducharme, Stephen; Fridkin, V.M.; Palto, S.P.; and Petukhova, N., "Evidence of dynamic Jahn-Teller distortions in two-dimensional crystalline molecular films" (1999 The surface electronic structure in crystalline copolymer films of vinylidene fluoride ͑70%͒ with trifluoroethylene ͑30%͒ has been studied by photoemission and inverse photoemission as a function of alkali metal ͑sodium͒ doping. Sodium doping introduces at least two new states into the band ͑HOMO-LUMO͒ gap well away from the Fermi level. While the sodium-doped copolymer is observed to resemble an n-type semiconductor, the change in electronic structure with temperature suggests that dynamic distortions lead to a photoemission initial state splitting of the lower Hubbard-like bands. There is a decrease in the effective Debye temperature with sodium doping which may, in turn, enhance the dynamic Jahn-Teller distortion.