Magnetic Properties and Crystal Structure of a Novel Di-μ-Formato-Bridged Binuclear Copper(II) Complex with 1,10-Phenanthroline

Abstract

A di-μ-formato-bridged binuclear copper(II) complex with 1,10-phenanthroline, [Cu(HCOO)(phen)(H2O)]2(NO3)2·4H2O, has been prepared and characterized by magnetic susceptibilities (80–300 K) and X-ray structure analysis. The magnetic data conform to the usual dimer equation with a singlet-triplet energy separation of −2J = 125 cm−1.

Magnetic properties and crystal structures of bis(μ-pyrazolato)-bridged dicopper(II,II) complexes with 1,10-phenanthroline or 2,2′-bipyridine

“…In addition, each copper ion slightly deviates from the equatorial planes towards the pyrazolate nitrogen by 0. 15 In 1, 2, 3ؒ2MeOH and 4ؒ2MeOH, the non-bonding ring-ring interactions are dominated by a stacking between the phen ligands. The shortest atom to atom distances within the stacking phen rings in each complex are in the 3.35-3.47 Å range.…”

Copper(II) Acetate as a Motif for Metal-Assembled Complexes

“…4 Type 1 25) Type 2 [25][26][27][28]58) Type 3a 29,57) Type3b 25,[27][28][29][30]61) syn-syn Type 4a 27,28,[31][32][33][34][35][36][37]39,[41][42][43][44][45][46][47][48]53,55,56,61,70) syn-anti Type 4b 38) 2 Type 5a 3 Type 5b 39) syn-syn Type 5c 40,53) cis-syn-anti Type 6c 49) Type 7 [50][51][52] syn-syn Type 8 53) syn-syn 2) R. J. Doedens, Prog. Inorg.…”

Di-μ-methacrylato-κ4O:O′-bis[aquabis(1,10-phenanthroline-κ2N,N′)copper(II)] dinitrate dihydrate

“…There is considerable interest in bioinorganic chemistry of metal carboxylates as these are formally analogous to organic esters (Dang, 1994;Reza et al, 2003). In this type of complex, the reactivity of the carboxylates towards the nucleophiles is enhanced (Houser et al, 1996;Blackburn et al, 1995;Reza et al, 1998;1999;Tokii et al, 1989). Since transition metal complexes of methacrylic acid are also polymeric (Schubert, 1996;Schubert et al, 1992Schubert et al, , 1995, chemists are attracted to study the application of these types of materials, particularly as catalysts.…”

“…For structures of related copper(II) complexes, see: Chen et al (2008); Perlepes et al (1995). For related literature, see: Besecke et al (1989); Blackburn et al (1995); Chen et al (2007); Dang (1994); Houser et al (1996); Matsushima et al (1995); Reza et al (1998Reza et al ( , 1999Reza et al ( , 2003; Tokii et al (1989Tokii et al ( , 1990Tokii et al ( , 1992Tokii et al ( , 1995; Schubert (1996); Schubert et al (1992Schubert et al ( , 1995. Symmetry codes: (i) Àx þ 1; y þ 1 2 ; Àz þ 1 2 ; (ii) Àx; y þ 1 2 ; Àz þ 1 2 ; (iii) x; Ày þ 1 2 ; z þ 1 2 ; (iv) x; y þ 1; z; (v) x; Ày þ 3 2 ; z þ 1 2 ; (vi) x; Ày þ 3 2 ; z À 1 2 .…”