2022
DOI: 10.1002/chem.202200399
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Mapping Catalyst–Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Abstract: Group 9 metals, in particular Rh III complexes with cyclopentadienyl ligands, are competent CÀ H activation catalysts. Recently, a Cp*Rh III -catalyzed reaction of alkenes with N-enoxyphthalimides showed divergent outcome based on the solvent, with carboamination favored in methanol and cyclopropanation in 2,2,2-trifluoroethanol (TFE). Here, we create selectivity and activity maps capable of unravelling the catalyst-solvent interplay on the outcome of these competing reactions by analyzing 42 cyclopentadienyl … Show more

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Cited by 2 publications
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References 91 publications
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