Mass spectrometric fragmentation reactions of dialkylselenides¹

Abstract

Mass spectrometric fragmentation and especially rearrangement reactions of dialkyl selenides after electron ionization will be discussed.

Intermediacy of ion neutral complexes in the fragmentation of short-chain dialkyl sulfides

“…n-Butyl methyl sulfide (1). In a 50 ml flask containing 20 ml of degassed H 2 O under N 2 , 2 g of NaOH and 4.5 g of n-C 4 H 9 SH are dissolved and 8.5 g of CH 3 13 C) are given in Table 1.…”