Material characterization combined with simple green chemistry method for integrated analysis of catalyst performance: A case study on MIL-53(Fe)

Liu, Xian; Xu, Cheng; Chen, Yu; Chen, Xueqi; Peng, Ke; He, Jiachen; Yu, Hao; Zhu, Lei; Wang, Xun

doi:10.1016/j.greeac.2022.100039

Cited by 6 publications

(2 citation statements)

References 34 publications

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“…MIL-53 (Al) exhibits a peculiar phenomenon known as "Breathing behavior" related to the hydrogen bonding interaction between the carboxylate groups of the BCD linker and the trapped water molecules, resulting in the contraction of its rhombic channels during hydration or dehydration. Compared with the strong adsorption capacity of MIL-53(Al), MIL-53(Fe) has higher light absorption performance [25]. Nevertheless, its adsorption capacity is weak due to its small specific surface area.…”

Section: Mil-53mentioning

confidence: 99%

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Recent Progress of MIL MOF Materials in Degradation of Organic Pollutants by Fenton Reaction

Xiao

Shu²,

et al. 2023

Catalysts

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In recent years, environmental pollution has become more serious, especially the organic pollutants. Metal organic frameworks (MOFs) are promising materials used to degrade pollutants recently. Among them, Materials Institute Lavoisier frameworks (MILs) have been widely engaged due to their good stability and unique structural characteristics. This paper systematically analyses and summarizes the progress of MILs in degradation of organic pollutant by Fenton reaction in recent years. The MILs, especially four types of MILs, including MIL-100, MIL-101, MIL-88, and MIL-53, are first described and classified. Then, the common synthesis methods (hydrothermal synthesis, steam-assisted synthesis, and microwave-assisted synthesis) of MIL are summarized and compared. Modification and activation of MILs to obtain good degradation effect are also introduced and discussed. Finally, the applications of MILs in Fenton reaction are reviewed and their future development is prospected.

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Section: Mil-53mentioning

confidence: 99%

“…and the trapped water molecules, resulting in the contraction of its rhombic channels during hydration or dehydration. Compared with the strong adsorption capacity of MIL-53(Al), MIL-53(Fe) has higher light absorption performance [25]. Nevertheless, its adsorption capacity is weak due to its small specific surface area.…”

Section: Mil-88mentioning

confidence: 99%