Mathematical Processing of Experimental Data Obtained with Ampoule and Titration Calorimeters Equipped with Different Types of Cells

Abstract

An algorithm is described for calculating the equilibrium constants and changes in the enthalpy of chemical reactions according to data from a calorimetric experiment performed on instruments of different types. Freeware is developed that executes the described algorithm. Differences from existing computer programs with similar functionality are briefly discussed, along with different statistical criteria of maximum likelihood.