A new gas chromatographic technique with a modified photoionization detector connected in series with a conventional flame ionization detector was used to determine low concentrations of atmospheric hydrocarbons in remote atmospheres. Average mixing ratios of five aromatic hydrocarbons measured between 42°N and 30°S latitude in the Pacific Ocean in October/November 1983 were highest in the Northern Hemisphere. The average mixing ratios in the northern and southern marine atmospheres were 49-+ 25 ppt (n = 35) and 10-+ 2 ppt (n = 21) for benzene, 20 + -12ppt (n = 32) and 5.6 -+ 1.6 ppt (n = 12) for toluene, 7.6 -+ 3.7 ppt (n = 35) and 3.7 -+ 1.6 ppt (n = 21) for ethylbenzene, 25 -+ 12 ppt (n --35) and 13 +-5 ppt (n = 20) for the sum of m-and p-xylenes, and 14 ± 6 ppt (n = 35) and 6.6 +-3.0 ppt (n = 21) for o-xylene, respectively. The first latitudinal gradients for these five aromatic compounds are reported. Benzene and toluene mixing ratios measured between July 1982 and October 1983 at a rural, mid-latitude continental site in eastern Washington state gave average values of 226 +-108 ppt and 133 +-84 ppt, respectively, with higher wintertime than summertime benzene levels. These continental samples gave calculated air mass ages averaging six days based on benzene-to-toluene ratios.