Natural Guar gum based resin which containing 6-amino caproic acid as a functional group has been synthesized. This modified ion exchange resin was used for removal of toxic metal ions from synthetic waste water using the principle of ion exchange mechanism. GACA resin was used for removal of Zn (II) and Co (II) metal ions from aqueous solution containing these metal ions. Zn (II) ion show maximum adsorption and Kd value at pH 5 while Co (II) show at pH 6. Zn (II) show maximum adsorption on GACA resin is 81.34% and for Co (II) is 73.3% which is good result.