Mechanistic studies on the formation of ternary oxides by thermal oxidation of the cubic laves phase CaAl2
Elias C. J. Gießelmann,
Stefan Engel,
Johannes G. Volpini
et al.
Abstract:Oxide materials are of key importance in many aspects of everyday life. However, their solid-state syntheses require high temperatures and often multiple steps when conducted from the binary oxides. Herein,...
As previously shown, CaAl2 can be oxidized using elemental O2 to form CaAl2O4. This reaction, however, proceeds via Ca12Al14O33 and elemental Al as intermediates which are subsequently transformed into the...
As previously shown, CaAl2 can be oxidized using elemental O2 to form CaAl2O4. This reaction, however, proceeds via Ca12Al14O33 and elemental Al as intermediates which are subsequently transformed into the...
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