2012
DOI: 10.1016/j.ssi.2012.06.008
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Mechanochemical synthesis of Li-argyrodite Li6PS5X (X=Cl, Br, I) as sulfur-based solid electrolytes for all solid state batteries application

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Cited by 430 publications
(389 citation statements)
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“…The mechanical milling was performed using a planetary ball mill with a zirconia pot with 0.5 g of sample and 10 mm diameter zirconia balls (15 balls) at 600 rpm for 40 h [ 6,16 ]. The as synthetized Li PS Cl powder was then dissolved in anhydrous ethanol (Wako Pure Chemicals, 99.5%).…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…The mechanical milling was performed using a planetary ball mill with a zirconia pot with 0.5 g of sample and 10 mm diameter zirconia balls (15 balls) at 600 rpm for 40 h [ 6,16 ]. The as synthetized Li PS Cl powder was then dissolved in anhydrous ethanol (Wako Pure Chemicals, 99.5%).…”
Section: Methodsmentioning
confidence: 99%
“…The XRD pattern of the as synthetized Li PS Cl solid electrolyte prepared by mechanical milling shows broad peak characteristic of the argyrodite crystal phase [ 16,17,18 ] and additional peaks attributed to the un reacted Li S phase. The XRD patterns of Li PS Cl crystals after dissolution reprecipitation procedure, with and without binder, show sharper peaks than those of Li PS Cl obtained by mechanical milling, confirming a higher crystallinity after dissolution reprecipitation procedure.…”
Section: Methodsmentioning
confidence: 99%
“…Studies investigating new electrolytes with much higher conductivity are in progress. Several crystals, such as Li10SnP2S12 (Boron et al, 2013) and Li6PS5Cl (Boulineau et al, 2012), have high conductivity of more than 10 −3 S cm…”
Section: Conductivitymentioning
confidence: 99%
“…The ionic conductivity of a Li 10 GeP 2 S 12 crystal, in particular, is 1.2 × 10 −2 S/cm (Kamaya et al, 2011). Argyrodite-type crystals with the stoichiometry Li 6 PS 5 X (X = Cl, Br, or I) also have high ionic conductivity (>10 −3 S/cm) (Deiseroth et al, 2008;Rao and Adams, 2011;Boulineau et al, 2012). In addition, the conductivities of some glasses, including 30Li 2 S-26B 2 S 3 -44LiI (Wada et al, 1983), 50Li 2 S-17P 2 S 5 -33LiBH 4 (Yamauchi et al, 2013), and 63Li 2 S-36SiS 2 -1Li 3 PO 4 (Aotani et al, 1994), have been reported to be as high as 1.5-1.7 × 10 −3 S/cm.…”
Section: Introductionmentioning
confidence: 99%