Organic triboluminescent (TL) crystals have attracted significant attention in recent years for their potential applications in various fields such as damage sensing in aerospace structures, cyanide detection in water, and radiation sensing. Europium tetrakis dibenzoylmethide triethylammonium (EuD4TEA) is a class of organic TL crystals that have shown promising results in terms of sensitivity due to their high TL intensity, however, they exhibit thermal instability and fragility concerns. In this review, recent research progress on the development, characterizations, TL properties, and potential applications of EuD4TEA crystals in various fields, are summarized. The review will conclude with the current challenges of EuD4TEA crystals, such as fragility nature, thermal instability, and increasing cost of europium. Despite having challenges, EuD4TEA crystals have the potential for damage sensing in the structural composite.