Mesogenic behaviour of isomeric bent-core 6-oxoverdazyls: 1,3-vrs 1,5-substitution pattern

Ciastek-Iskrzycka, Sylwia; Gerding, Jason S.; Kaszyński, Piotr; Pociecha, Damian

doi:10.1080/02678292.2018.1441454

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Cited by 6 publications

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“…One of the classes of liquid crystalline stable radicals is based on the 6-oxoverdazyl radical, [28][29][30][31][32][33][34][35] which includes a series of bent-core 1,5-bis(aryloiloxyphenyl)-6-oxoverdazyls 1[m,n] (Fig. 1).…”

Section: Introductionmentioning

confidence: 99%

Mesogenic behavior of a 6-oxoverdazyl diradical: towards organic high-spin liquid crystals

Kapuściński,

Szczytko,

Pociecha

et al. 2024

Mater. Chem. Front.

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Section: Introductionmentioning

confidence: 99%

Mesogenic behavior of a 6-oxoverdazyl diradical: towards organic high-spin liquid crystals

Kapuściński,

Szczytko,

Pociecha

et al. 2024

Mater. Chem. Front.

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Paramagnetic Liquid Crystals With Close π–π Packing: The Effect of Blatter Radical Planarization on Behavior of Bent‐Core Mesogens

Cigl

Pociecha

Jakubowski

et al. 2023

Chemistry A European J

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A new, 19 π-delocalized electrons planar Blatter radical building block was developed and used to obtain paramagnetic bent-core liquid crystals. The mesogens were investigated by optical, thermal, powder XRD and DFT methods in the pure form and as binary mixtures. Comparison of their properties with those of the classical Blatter radical analogues revealed that planarization of the central angular element results in a significantly higher stability of the mesophases and increased molecular organization suitable for the formation of ordered banana and columnar mesophases with tighter π-π interactions. These results indicate access to a new, potentially rich class of functional paramagnetic soft materials.

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Liquid crystalline derivatives of heterocyclic radicals

Kaszyński

Kapuściński

Ciastek-Iskrzycka

2019

Advances in Heterocyclic Chemistry

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Mesogenic behaviour of isomeric bent-core 6-oxoverdazyls: 1,3-vrs 1,5-substitution pattern

Cited by 6 publications

References 20 publications

Mesogenic behavior of a 6-oxoverdazyl diradical: towards organic high-spin liquid crystals

Mesogenic behavior of a 6-oxoverdazyl diradical: towards organic high-spin liquid crystals

Paramagnetic Liquid Crystals With Close π–π Packing: The Effect of Blatter Radical Planarization on Behavior of Bent‐Core Mesogens

Liquid crystalline derivatives of heterocyclic radicals

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