Metal benzoylpivaloylmethanates

Kwiatkowski, Edmund; Nowicki, W.; Szyncel, M.

doi:10.1016/0040-6031(94)80067-7

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1997

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“…From UV, IR, and 1 H NMR spectroscopy − it was concluded that the diketone exists mainly as PhCOCH(OH)CMe 3 (Ph, phenyl; Me, methyl). Up to now, only benzoylpivaloylmethanide complexes with alkaline earth and transition metals have been described in the literature Y(bpm) 3 is obtained as the monohydrate, which tends to form an oil.…”

Section: Resultsmentioning

confidence: 99%

Benzoylpivaloylmethanide Precursors for the Chemical Beam Epitaxy of Oxide Thin Films. 1. Synthesis, Characterization, and Use of Yttrium Benzoylpivaloylmethanide

et al. 1997

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The new complex yttrium benzoylpivaloylmethanide and its acetonitrile adduct have been characterized by IR, NMR, mass spectroscopy, X-ray structure analysis, and thermogravimetric/differential thermal analysis. In situ flux measurements and mass spectroscopic studies have been performed to test the suitability of this compound as a precursor for the deposition of complex oxide thin films under molecular beam conditions. Finally it has been used to deposit epitaxial Y2O3 (001) thin films on SrTiO3 (001) substrates.

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