Metal organic framework–organic polymer monolith stationary phases for capillary electrochromatography and nano-liquid chromatography

Recent advances in solid-phase sorbents for sample preparation prior to chromatographic analysis

“…MOFs used as chromatographic solid phases were also investigated [206][207][208] {e.g., a tubular MOF, MOF-CJ3, was chosen as stationary phase to prepare a capillary GC column via a verified dynamic coating procedure. The column offered good separations of linear and branched alkanes, as well as aromatic positional isomers [206]}.…”

Pressure inverse solubility and polymorphism of an edible γ-cyclodextrin-based metal–organic framework

“…Owing to their large active area, as well as their structural and functional diversity, MOFs have various applications in industry and science. [2][3][4][5][6][7][8][9] For example, they are promising materials for increasing the efficiency of fuel gas storage. 10,11 However, most MOFs and their syntheses are toxic, which limits their applicability.…”

Fabrication of zeolitic imidazolate framework-8-methacrylate monolith composite capillary columns for fast gas chromatographic separation of small molecules

“…One of the most convenient methods used to enhance the separation of small molecules using polymeric monoliths is the incorporation of various nano-and micro-particles into the monolithic matrix. Several attempts have successfully been made using this technique, including carbon nanotube (CNT) [2][3][4][5], graphene oxide (GO) [6], C 60 -fullerene [7], sporopollenin [8], and metal-organic frameworks [9][10][11].…”

“…Although using MOFs in chromatography has already given promising and surprising results, the use of MOFs incorporated with polymers (MOF-polymer) to form a composite stationary phase is still very limited [9][10][11]. The composite material combines the advantages of the MOF stationary phase and the monolithic organic stationary phase and avoids their disadvantages.…”