Metal-organic frameworks as potential catalysts for biodiesel production and biomass conversion: Mechanism and characteristics

Le, Thanh Tuan; Sharma, Prabhakar; Le, Huu Son; Le, Huu Cuong; Le, Duc Trong Nguyen; Cao, Dao Nam; Truong, Thanh Hai; Tran, Viet Dung

doi:10.1016/j.indcrop.2024.118232

Cited by 4 publications

(1 citation statement)

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“…At the heart of MOF catalysis lies the coordination chemistry between metal nodes and organic linkers, which creates a diverse array of active sites with varying chemical environments. During biomass conversion, reactant molecules interact with these active sites, undergoing a series of adsorption, activation, and transformation steps. , There are several factors that influence the catalytic performance of MOFs during biomass conversion. These include the composition and structure of MOFs, the nature of active sites, surface area, pore size distribution, and surface functionalization.…”

Section: Metal-organic Frameworkmentioning

confidence: 99%

Sustainable Porous Heterogeneous Catalysts for the Conversion of Biomass into Renewable Energy Products

Mondal,

Ruidas,

Chongdar

et al. 2024

ACS Sustainable Resour. Manage.

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Bioenergy possesses the potential to alleviate our energy demands while maintaining renewability and carbon neutrality. The utilization of abundant biomass sources for bioenergy production presents a significant challenge. When considering chemical processes for conversion, the development of effective catalysts becomes imperative as they play a pivotal role in biomass-to-bioenergy/biofuel conversion. In such scenarios, heterogeneous nanoporous materials emerge as crucial components for facilitating catalytic conversion. This perspective provides a comprehensive summary of biomass, including its classification, valorization processes and applications along with recent advancements in various catalytic systems utilized for transforming biomass and its intermediates into renewable energy products. We delved into the diverse classes of heterogeneous catalysts, including metal-based, metal oxide-based, silica based, hybrid catalysts, and organic polymers, highlighting their unique structural and compositional features that influence catalytic activity and selectivity. Furthermore, we discussed the importance of pore structure, surface area, and active site accessibility in enhancing catalytic performance. By examining the advantages and limitations of different catalysts, we provide insights into the rational design and optimization of porous heterogeneous catalysts for efficient and sustainable bioenergy conversion. This perspective serves as a valuable resource for researchers and engineers in the field of renewable energy, seeking to develop innovative catalyst materials for biomass valorization.

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Section: Metal-organic Frameworkmentioning

confidence: 99%