Metallocene-containing conjugated polymers

Vorotyntsev, Mikhail A.; Vasilyeva, Svetlana V.

doi:10.1016/j.cis.2008.01.006

Cited by 59 publications

(35 citation statements)

References 442 publications

(497 reference statements)

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“…Polymers and metal oxides have been studied for many years for their independent electrical, optical, and mechanical properties [5]. Composites of these polymers with inorganic matter, combining the different properties of components, are considered remarkable advanced materials [6]. Polythiophene (PT) was widely studied as donor material in organic solar cells [7,8].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and application of solar cells of poly (3-decylthiophene)/N/titanium dioxide hybrid

Zhang¹,

Zheng²,

Chen³

et al. 2011

Express Polym. Lett.

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Abstract. An organic-inorganic nanocomposite material of poly (3-decylthiophene) and titanium dioxide doped with N (P3DT/N/TiO 2 ) were synthesized. Structures were characterized using X-ray diffraction (XRD), infrared spectroscopy (IR), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). Optical and electrochemical properties were determined using UV-visible spectroscopy, fluorescence spectroscopy, and cyclic voltammetry. These tests indicated that P3DT/N/TiO 2 was a new p-n semiconductor photoelectric material, and the solar cell prepared with P3DT/N/TiO 2 performed well.

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Section: Introductionmentioning

confidence: 99%

Synthesis and application of solar cells of poly (3-decylthiophene)/N/titanium dioxide hybrid

Zhang¹,

Zheng²,

Chen³

et al. 2011

Express Polym. Lett.

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“…ammonium salts) groups that either accept or release protons in response to changes in environmental pH [23] . Polyacrylic acid, poly(methacrylic acid), poly(2 -ethylacrylic acid), poly(2 -propylacrylic acid), and polysulfonamides (derivatives of p -aminobenzenesulfonamide) are a few examples of poly acids (anionic polymers).…”

Section: P H -Sensitive Nanofi Bersmentioning

confidence: 99%

“…In this context, the use of nanomaterials to fabricate smart materials is one of the most exciting approaches because nanomaterials have a unique structure and high surface -to -volume ratio [23] . The surfaces of nanomaterials can also be tailored at the molecular scale in order to achieve various desirable properties [24] .…”

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confidence: 99%

Smart Polymeric Nanofibers Resolving Biorecognition Issues

Tiwari

Mishra

et al. 2011

Biosensor Nanomaterials

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Smart materials are a class of materials having one or more properties that can be signifi cantly changed in a controlled manner by changing the external stimuli, such as stress, temperature, moisture, pH, electric, and magnetic fi elds. There are numerous types of smart materials; however, we can categorize them on the basis of their responsive behaviors during the stimuli. " Piezoelectric materials " are ceramics or polymers characterized by a swift, linear shape change in response to an electric fi eld. The electricity makes the material expand or instantly contract. This class of materials has potential applications in actuators to control chatter in precision machine tools, improve robotic parts for faster and accurate movement, microelectronic circuits in machines (e.g., computers, photolithography printers, etc.), and also in integrity -monitoring fi bers for bridges, buildings, and wood utility poles [1] . " Electrostrictive and magnetostrictive materials " show a change in material size with response to either an electric or magnetic fi eld, and conversely produce a voltage when stretched. These materials show promising applications for the manufacturing of pumps and valves, aerospace wind tunnels, shock -tube instrumentation, landing gear hydraulics, and further biomechanics force measurement of orthopedic gait and posturography, sports, ergonomics, neurology, cardiology, and rehabilitation [2] . " Rheological materials " are smart materials that include not only solids, but also fl uids like electrorheological and magnetorheological fl uids that can change state instantly using an electric or magnetic fi eld [3] . These types of fl uids being used as dampers for vehicle seats, shock absorbers, exercise equipment, and optical fi nishing. " Thermo -responsive materials, " such as shape memory alloys, show a change in shape in response to heat and/or cold. Nitinol or nickel and titanium are usually combined to form such intelligent materials. The rarely used materials for this class are Au/Cd, Ag/Cd, Cu/Al/Ni, Cu/Sn, and Cu/Zn/Al [4] . They are frequently used in couplers, thermostats, and automobile, plane and helicopter parts. " pH -sensitive " materials are used as indicators and can change color as a function of pH. This type of smart material shows promise in paints

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“…The accumulation of a great number of studies on nanocomposite materials has provoked the recent appearance of several review articles [2-7] attempting to summarize, from different specific points of view, the advances made in the field. Thus, electrochemical aspects [2,7] of CP-based composites, optical and electronic properties [3], polyaniline(PANI)-based nanocomposites [4], the involvement of composites of CPs in chemical sensing [5], and the incorporation of metallocenes in CPs [6] have been extensively discussed.…”

Section: Introductionmentioning

confidence: 99%

Metallic‐Based Nanocomposites of Conductive Polymers

Tsakova

2010

Nanostructured Conductive Polymers

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IntroductionSince the remarkable discovery of high electrical conductivity in polymer materials in 1977 [1], studies on conductive polymers (CP 1 ) have developed into interdisciplinary research expanding in various directions. A significant impetus to the field was given by materials scientists in their attempts to combine the unique properties of conductive polymers with those of other inorganic and organic materials. Thus, in the last two decades, research on the synthesis of CP-based composite materials has flourished and resulted in the development of a great variety of new materials with interesting specifically designed properties. The accumulation of a great number of studies on nanocomposite materials has provoked the recent appearance of several review articles [2-7] attempting to summarize, from different specific points of view, the advances made in the field. Thus, electrochemical aspects [2,7] of CP-based composites, optical and electronic properties [3], polyaniline(PANI)-based nanocomposites [4], the involvement of composites of CPs in chemical sensing [5], and the incorporation of metallocenes in CPs [6] have been extensively discussed.

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Metallocene-containing conjugated polymers

Cited by 59 publications

References 442 publications

Synthesis and application of solar cells of poly (3-decylthiophene)/N/titanium dioxide hybrid

Synthesis and application of solar cells of poly (3-decylthiophene)/N/titanium dioxide hybrid

Smart Polymeric Nanofibers Resolving Biorecognition Issues

Metallic‐Based Nanocomposites of Conductive Polymers

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