Methanation Pilot Plant with a Slurry Bubble Column Reactor: Setup and First Experimental Results

Abstract

As a part of various research projects, a methanation pilot plant with a slurry bubble column reactor (SBCR) was commissioned and operated. The plant has a nominal load of a 100 kW methane output (lower calorific value) with a reactor diameter of 260 mm and a reactor length of 2500 mm. First experimental data on the steady-state and dynamic operation of catalytic CO2 methanation are presented. Steady-state results from laboratory-scale studies (<1 kW methane output) published previously were confirmed qualitatively at the pilot plant eliminating wall effects unavoidable in small-scale reactors. As predicted, high H2/CO2 ratios increase CO2 conversion, but excess H2 apparently promotes decomposition of the liquid phase (dibenzyltoluene) used in the bubble column reactor. Additionally, due to the increased reactor dimensions compared to laboratory equipment, it was now possible to observe a thermal response of the SBCR under conditions of rapid gas load changes characteristic of envisaged power-to-gas applications with volatile renewable electricity. As the predicted robustness of the SBCR-concept toward a dynamic operation with fast load changes was demonstrated successfully, it offers an attractive alternative to the established fixed-bed methanation technologies with their inherent limitations on dynamic operability.

Microbial electrosynthesis: carbonaceous electrode materials for CO2 conversion

“…Since mechanical mixing and operation in various modes are not necessary, bubble column reactors have low maintenance and operating expenses. Its drawbacks include the need to optimize bubble size for successful mass transfer 44 .…”

“…Its drawbacks include the need to optimize bubble size for successful mass transfer. 44 Biofilm-coated anodes have been commonly utilized in microbial fuel cells (MFC) to convert chemical energy into electricity. 45 Recently, a microbial carbon capture (MCC) technology has been established through the utilization of biofilm-coated anode and cathode.…”

Trendbericht Technische Chemie 2023

“…42 -44) Eine ähnliche Leistung erzielten Blasensäulenreaktoren für die Methanisierung. 45) Das Fluidisierungsregime kann ausgeprägte Hotspots vermeiden und so die Leistung des Systems verbessern. Folglich ist der Wirbelschichtreaktor unter bestimmten Bedingungen aus wirtschaftlicher Sicht eine vielversprechendere Lösung als der Festbettreaktor.…”

Efficient Utilization of Carbon Dioxide in Power-to-Gas and Power-to-Liquid Processes: A Vital Path to Carbon Neutrality

“…It is due to the fact that the inert liquid has a relatively large heat capacity. However, the evaporation and decomposition of the inert liquid are significant issues for three-phase reactors [32]. Table 1 presents the comparison of the reactor performance in the methanation process.…”

“…Table 1 presents the comparison of the reactor performance in the methanation process. [26,28,29,32].…”