As an extension of intuitionistic fuzzy sets (IFSs), picture fuzzy sets (PFSs) can better model and represent the hesitancy and uncertainty of decision makers’ preference information. In this study, we propose a multicriteria group decision making (MCGMD) method based on picture fuzzy sets. We first define some basic picture Einstein operations with closed properties among PFSs on the basis of the Einstein t-norms and t-conorms. Then, utilizing the hybrid-weighted operator and the developed picture Einstein operations laws, we put forward a picture fuzzy Einstein hybrid-weighted aggregation operator for aggregating PFSs and discuss its several important properties. Furthermore, we present a new MCGMD method based on the proposed picture fuzzy Einstein hybrid-weighted aggregation operator. Finally, an example is conducted to validate the effectiveness of the proposed MCGMD method.