Methods for the Introduction of the Phosphonate Moiety into Complex Organic Molecules

doi:10.1002/9783527672240.ch7

Organophosphorus Chemistry 2019

DOI: 10.1002/9783527672240.ch7

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Methods for the Introduction of the Phosphonate Moiety into Complex Organic Molecules

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Cited by 4 publications

References 248 publications

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Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐a]Pyridin‐2‐yl)Phosphonates

Roscales,

Csáky

2024

Angewandte Chemie

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We report a novel, metal‐free procedure for the direct aminophosphonation of imidazo[1,2‐a]pyridines in green solvents under open air conditions. This method is characterized by its mild and sustainable conditions, ease of operation, scalability, and excellent functional group compatibility. The synthesized compounds exhibit promising photophysical properties, including significant Stokes shifts and quantum yields, making them potential candidates for innovative fluorescent probes.

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Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐a]Pyridin‐2‐yl)Phosphonates

Roscales,

Csáky

2024

Angewandte Chemie

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Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐a]Pyridin‐2‐yl)Phosphonates

Roscales,

Csáky

2024

Angew Chem Int Ed

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Electrochemical Phosphorylation of Organic Molecules

Sbei

Martins

Shirinfar

et al. 2020

The Chemical Record

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Organophosphorus chemistry is a broad field with multi-dimensional applications in research area of organic, biology, drug design and agrochemicals. Conventional methods have been adopted extensively to access phosphorylated compounds that rely on the use of toxic, moisture sensitive phosphorylating agents and occur in the presence of oxidants, catalysts, as well as high temperatures and harsh conditions are required for complete transformations. However, recent progress has been made for phosphorylation reactions using electricity to introduce green and sustainable synthetic procedures. These reactions can be performed at mild conditions and proceed with excellent atom economy. Herein, we targeted electrochemical phosphorylation reactions with generation of new bonds such as C(sp 3) À P, C(sp 2) À P, OÀ P, NÀ P, SÀ P and SeÀ P. This review is aimed to offer an overview of recent developments in the synthetic methodology to easy access of organophosphorus compounds using electrochemistry.

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Methods for the Introduction of the Phosphonate Moiety into Complex Organic Molecules

Cited by 4 publications

References 248 publications

Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐a]Pyridin‐2‐yl)Phosphonates

Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐a]Pyridin‐2‐yl)Phosphonates

Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐a]Pyridin‐2‐yl)Phosphonates

Electrochemical Phosphorylation of Organic Molecules

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