Methyl 4-benzyloxy-2-hydroxybenzoate

Abstract

In the title compound, C15H14O4, the dihedral angle between the benzene rings is 67.18 (8)°. The Ca—Cm—O—Ca (a = aromatic and m = methyl­ene) torsion angle is 172.6 (3)° and an intra­molecular O—H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds into zigzag chains propagating in [001] and C—H⋯π inter­actions also occur.

Crystal structure of 1-{4-hydroxy-3-[(pyrrolidin-1-yl)methyl]phenyl}-3-phenylprop-2-en-1-one

“…The central benzene ring (C10-C15) makes dihedral angles of 21.39 (10) and 80.10 (15) , with the phenyl ring (C1-C6) and the mean plane of the pyrrolidine ring (N1/C17-C20), respectively. Otherwise, the geometrical parameters for (I) are comparable those reported for related compounds (Suhud et al, 2015;Palakshamurthy et al, 2012). An intramolecular O2-H1OÁ Á ÁN1 hydrogen bond (Table 1, Fig.…”