In this article, gradient-distributed VCp-ZTAp/Fe45 composites were prepared by vacuum sintering, and three-body abrasive wear experiments were carried out to investigate its anti-wear performance. The composite casting of VCp-ZTAp/Fe45 was investigated by using the finite element method and experiments, and the bonding between the Fe45 substrate and 35SiMnCrMoNi steel was fully investigated. Results show the in situ formation of VCp in the VCp-ZTAp/Fe45 composite matrix during vacuum sintering. The anti-wear property of the VCp-ZTAp/Fe45 composite is ca. 7 times that of Hardox450 and NM450 and ca. 8 times of 30SiMn. There forms a solid metallurgical bonding between the Fe45 matrix of VCp-ZTAp/Fe45 and 35SiMnCrMoNi steel, with a ca. 80 μm thickness of the bonding area during the composite casting.