Among nanocarbon filler, carbon nanotubes (CNTs) are considered to be an ideal reinforcement due to their miniscule size, and excellent electrical, thermal, and mechanical properties. However, CNTs can be utilized in polymer nanocomposites only if they are homogenously dispersed into polymer matrices. The multi-walled carbon nanotube (MWCNTs) has been concentrated as reinforcement for an important type of thermoplastic polyvinylidene fluoride (PVDF). This review firstly focuses on CNTs modification both by mechanical methods and chemical functionalization to improve their dispersion. Moreover, processing methods for PVDF/CNTs nanocomposite have been discussed. MWCNTs facilitate the electrical conductivity, thermal, rheological and mechanical properties of PVDF.