MIL-68 derived In2O3 microtubes and Co3O4/In2O3 heterostructures for high sensitive formaldehyde gas sensors

Kong, D.L.; Wu, W.J.; Hong, B.; Xu, J.C.; Peng, X.L.; Ge, H.L.; Li, J.; Zeng, Y.X.; Wang, X.Q.

doi:10.1016/j.ceramint.2023.12.051

Cited by 11 publications

(1 citation statement)

References 74 publications

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“…The World Health Organization (WHO) guidelines have set an exposure threshold value of 82 ppb for HCHO in indoor living areas [4]. At present, metal oxide semiconductor (MOS)-based sensors are one of the effective methods for monitoring indoor HCHO with higher sensitivity and shorter reaction times [5,6]. However, the high-power consumption of MOS sensors and the susceptibility of their sensitivity to ambient humidity are the main drawbacks that affect the reliability of gas sensors in practical applications [7].…”

Section: Introductionmentioning

confidence: 99%

Synergistic Effect of ZIF-8 and Pt-Functionalized NiO/In2O3 Hollow Nanofibers for Highly Sensitive Detection of Formaldehyde

Zhu,

Wang,

Wang

et al. 2024

Nanomaterials

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A rapid and accurate monitoring of hazardous formaldehyde (HCHO) gas is extremely essential for health protection. However, the high-power consumption and humidity interference still hinder the application of HCHO gas sensors. Hence, zeolitic imidazolate framework-8 (ZIF-8)-loaded Pt-NiO/In2O3 hollow nanofibers (ZPNiIn HNFs) were designed via the electrospinning technique followed by hydrothermal treatment, aiming to enable a synergistic advantage of the surface modification and the construction of a p-n heterostructure to improve the sensing performance of the HCHO gas sensor. The ZPNiIn HNF sensor has a response value of 52.8 to 100 ppm HCHO, a nearly 4-fold enhancement over a pristine In2O3 sensor, at a moderately low temperature of 180 °C, along with rapid response/recovery speed (8/17 s) and excellent humidity tolerance. These enhanced sensing properties can be attributed to the Pt catalysts boosting the catalytic activity, the p-n heterojunctions facilitating the chemical reaction, and the appropriate ZIF-8 loading providing a hydrophobic surface. Our research presents an effective sensing material design strategy for inspiring the development of cost-effective sensors for the accurate detection of indoor HCHO hazardous gas.

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