The purpose of this research was to process a mixture of paper waste and garden waste based on material flow analysis and to analyze its parameters based on water content, ash content, heating value, along with Thermogravimetry Analysis (TGA)/Derivative Thermogravimetry (DTG). The garden waste treatment process consists of shredding, drying with a rotary dryer, separator, and then shaving with a hammer mill. Paper waste only needs a shredder process. Then, the mixing process and pelletizing of paper waste as well as garden waste are carried out according to the variation (w/w) 100% paper (K100), 75% paper (K75), 50% paper (K50), 25% paper (K25), and 100% garden waste (K0). The water content ranged from 5.8 to 15.25%. From K0 to K100 samples, the ash content increased from 4.54 to 9.85%. A correlation of 0.9047 was found from samples K0 to K100. There was a correlation between increasing calorific value along with the mixture with paper waste. The caloric value in K0 to K100 increased from 13.11 to 19.03 MJ/kg. The TGA/DTG analysis reduced mass due to water evaporation, devolatilization, and carbonization processes.