2010
DOI: 10.1002/anie.200906642
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Modular Inorganic Nanocomposites by Conversion of Nanocrystal Superlattices

Abstract: Inorganic nanocomposites have been prepared by assembling colloidal nanocrystals and then replacing the organic ligands with precursors to an inorganic matrix phase. Separate synthesis and processing of the nanocrystal and matrix phases allows complete compositional modularity and retention of the superlattice morphologies for sphere (see scheme; top) or rod (bottom) assemblies.

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Cited by 65 publications
(84 citation statements)
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“…147 Binder and co-workers employed 1,2-diols bearing o-azido or o-bromo ligands to replace octylamine or oleic acid on g-Fe 2 O 3 nanoparticles followed by post-functionalization of the new ligand to obtain fluorescent properties. [152][153][154][155][156][157][158][159][160] Polymer ligands. 149 Hatton and colleagues replaced oleic acid with various hydroxyl group-containing ligands.…”
Section: Non-charged Moietiesmentioning
confidence: 99%
“…147 Binder and co-workers employed 1,2-diols bearing o-azido or o-bromo ligands to replace octylamine or oleic acid on g-Fe 2 O 3 nanoparticles followed by post-functionalization of the new ligand to obtain fluorescent properties. [152][153][154][155][156][157][158][159][160] Polymer ligands. 149 Hatton and colleagues replaced oleic acid with various hydroxyl group-containing ligands.…”
Section: Non-charged Moietiesmentioning
confidence: 99%
“…This concept of separating nanoparticle synthesis and nanocomposite formation has been previously demonstrated to produce nanocomposites with organic matrices [43][44][45] , oxide matrices 46, 47 and semiconductor matrices. [48][49][50] Herein, we have applied this concept to metal matrix nanocomposites. We do note that identifying appropriate metal precursors is not trivial because many precursors decompose into metal-oxide instead of metal.…”
Section: Metal Matrix -Metal Nanoparticle Composite Synthesismentioning
confidence: 99%
“…In order to use the nanocrystals for these applications, size and shape control of the nanocrystals and development of "bottom-up" process are most important. 4,5 However, there have been only a few reports on dielectric and ferroelectric nanocubes and their potential applications so far. Barium titanate (BT) and strontium titanate (ST) are the most popular perovskite oxides for electronic device application such as multilayered ceramic capacitor (MLCC), positive temperature coefficient (PTC) thermistor, and so on.…”
mentioning
confidence: 99%