MOF-derived Co, Fe, and Ni co-doped N-enriched hollow carbon as efficient electrocatalyst for oxygen reduction reaction

Jing, Yanqiu; Cheng, Yuyuan; Wang, Lin; Liu, Yuan; Yu, Baohua; Yang, Chao

doi:10.1016/j.cej.2020.125539

Cited by 116 publications

(50 citation statements)

References 36 publications

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“…21 The mechanism of activity promotion is usually known as the synergistic effect between the novel metal and MnO x . 22–24 It is worth noting that Co-based materials can greatly promote the ORR performance of materials due to their comparable catalytic activity and good resistance in alkaline solution. 25–30 Therefore, using the synergistic integration of metallic Co with MnO x is a rational strategy to design a bifunctional catalyst for the ORR/OER.…”

Section: Introductionmentioning

confidence: 99%

Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn–air batteries

Zhou

Liu

et al. 2022

Sustainable Energy Fuels

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Section: Introductionmentioning

confidence: 99%

Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn–air batteries

Zhou

Liu

et al. 2022

Sustainable Energy Fuels

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“…Therefore, more and more people use MOF-derived carbon-based materials in various electrocatalytic reactions by optimizing synthesis strategies. [34][35][36][37][38][39][40][41][42][43] Recent researches show that the confinement engineering of MOF-derived carbon-based electrocatalysts has offered inspiring confinement effect when applied to electrocatalysis, which concerning the following two aspects. Firstly, the confinement engineering can disperse and stabilize single atoms, clusters, or nanoparticles (NPs) through space confinement to prevent agglomeration and improve the durability of the catalyst.…”

Section: Introductionmentioning

confidence: 99%

Rational confinement engineering of MOF‐derived carbon‐based electrocatalysts toward CO₂ reduction and O₂ reduction reactions

Zhang

Xue

Jiang

et al. 2021

InfoMat

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The goal of global carbon peak and neutrality gives an impetus to the utilization of clean energy (e.g., fuel cell) and carbon dioxide (CO 2 ) at a large scale, where the oxygen reduction reaction (ORR) and CO 2 reduction reaction (CO 2 RR) are the key reactions via the sustainable system, respectively. As a main precursor for fabricating affordable carbon-based electrocatalysts with uniformly dispersed active centers and tailorable performances for ORR and CO 2 RR, metal organic frameworks (MOFs) have captured a surge of interest in recent years. Despite the facilitated development of MOF-derived carbon-based electrocatalysts by many investigations, it is still plagued by high overpotential and unsatisfied life span, which are greatly determined by the efficient and alterable confinement effect on synthesis and performance. In this review, firstly, the confined synthetic strategies (doping engineering, defect engineering, geometric engineering, etc.) of MOF-derived carbon-based electrocatalysts with multi-sized active centers (atom, atomic clusters and nanoparticles (NPs)) are systematically summarized; secondly, the confinement effect on the interaction of ORR and CO 2 RR intermediates, as well as the catalytic durability and activity, was discussed from chemical and physical aspects. In the end, the review discusses the remaining challenges and emerging research topics in the future, including support upgradation and catalyst innovation, high selectivity and effective confinement synthesis, in situ and operando characterization techniques, theoretical investigation, and artificial intelligence (AI) assistant. The new understanding and insights into these aspects will guide the rational confinement concept of MOF-derived carbon-based electrocatalysts for ORR and CO 2 RR with optimized performances in terms of confinement engineering and are believed to be helpful for filling the existing gaps between scientific communities and practical use.Xiaoyu Zhang and Dongping Xue contribute equally to this work.

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“…Clearly, inventing new high-activity nonprecious metal (NPM) ORR catalysts to replace Pt-based catalysts is critical. [10] In the last decades, there have been several reports on non-precious electrocatalysts such as inorganic nanoparticles (Cu1.4Mn1.6O4, TaCxFyOz/ g C, Ru), [11][12][13] transition metalnitrogen-carbon catalysts (Mn, Fe, Co and Ni based, Fe/Co containing N-doped porous carbon; iron-nitrogen/carbon), [14][15][16][17][18][19][20][21] transition metal oxides (Fe@Fe2O3), [22,23] non-metal (N, P, S, F etc) doped carbon materials, [24][25][26][27][28][29][30] CNT, [29,31] metal organic framework (MOF) based porous carbon [17,[32][33][34] etc. based electroactive materials have gained significant attention in order to overcome the cost and sluggish reaction kinetics of ORR.…”

Section: Introductionmentioning

confidence: 99%

Bagasse derived C@Fe3C/Fe3O4 composite: An Approach towards low cost electrocatalyst for oxygen reduction reaction

Manippady

Khan

Samal

et al. 2021

Preprint

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As the world is heading towards sustainable future, it is highly important to develop low-cost electrocatalysts for energy generation devices. Herein, we report synthesis of iron-carbon hybrid (C@Fe3C/Fe3O4) nanocomposite for oxygen reduction reaction (ORR), synthesized using bagasse as a carbon source material and Fe(III) precursor at 900 ˚C. The synthesized C@Fe3C/Fe3O4 composite exhibits a high surface area of ~930 m2/g. The electrode material has a 0.86 V overpotential vs RHE. Moreover, the electrocatalyst shows catalytic stability upto 44,000 s at the static potential of 0.25 V vs RHE at the rotation speed of 1600 rpm. Herein, the electron transfer number is calculated to be 3.76-3.94 which suggest that the electrocatalyst could catalyze ORR nearly through a 4 electron transfer process in alkaline solution.

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MOF-derived Co, Fe, and Ni co-doped N-enriched hollow carbon as efficient electrocatalyst for oxygen reduction reaction

Cited by 116 publications

References 36 publications

Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn–air batteries

Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn–air batteries

Rational confinement engineering of MOF‐derived carbon‐based electrocatalysts toward CO₂ reduction and O₂ reduction reactions

Bagasse derived C@Fe3C/Fe3O4 composite: An Approach towards low cost electrocatalyst for oxygen reduction reaction

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MOF-derived Co, Fe, and Ni co-doped N-enriched hollow carbon as efficient electrocatalyst for oxygen reduction reaction

Cited by 116 publications

References 36 publications

Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn–air batteries

Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn–air batteries

Rational confinement engineering of MOF‐derived carbon‐based electrocatalysts toward CO2 reduction and O2 reduction reactions

Bagasse derived C@Fe3C/Fe3O4 composite: An Approach towards low cost electrocatalyst for oxygen reduction reaction

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Rational confinement engineering of MOF‐derived carbon‐based electrocatalysts toward CO₂ reduction and O₂ reduction reactions