Molecular and crystal structure of a sterically distorted complex of Pd(II) with 2,9-dimethyl-1,10-phenanthroline [Pd(2,9-Me2-phen)Cl2]

Single Isolated Pd2+ Cations Supported on N-Doped Carbon as Active Sites for Hydrogen Production from Formic Acid Decomposition

“…The structure of some complexes of Pd with this ligand is well studied. [48][49][50] These complexes were used as homogeneous catalysts for different reactions. Thus, recently it was shown that complexes of some noble metals 51 and iron 52 with phenanthroline type ligands are active in conversion of CO 2 to formate species 51 and in dehydrogenation of formic acid.…”

Unexpected isomerism in “[Pd(2,9-dimethylphenanthroline)X2]” (X = Cl, Br, I) complexes: a neutral and an ionic form exist

“…A solid state form of compound 1a has recently been reported, 44 but the form we obtained (1a• 1 2 CH 2 Cl 2 ) is a pseudopolymorph, having the crystallisation solvent co-crystallised (in a ratio 1 : 2). The space group type of 1a and 1a• 1 2 CH 2 Cl 2 is incidentally the same (P2 1 /n, keeping the same setting adopted in ref.…”

Reaction with DNA and pharmacologic activity of 1,10-phenanthroline and electron-rich 1,10-phenanthrocyanine complexes of d-elements

“…[127] employed spectral and hydrodynamic methods to study complex formation with a high-molecular thymus DNA (relative molecular weight 8×10 6 ) of a sterially distorted Pd(II) 2,9-dimethyl-1,10-phenanthroline complex A characteristic feature of this compound is that it when crystallized from solutions, forms π-π-stacking columnar structures from π-π-stacking dimers ( Fig. 2) [128].…”

“…We developed syntheses and studied the coordination compounds of a new structural class of cyanines, specifically electron-excessive supramolecular (glassy in the solid state and colloid in solutions) complexes of 1,10-phenanthrocyanines with the transition methals Ni(II), Pd(II), and Pt(II) (configuration d 8 ), Co(II) (d 7 ), Cr(III) (d 3 ), Rh(III) (d 6 ), and Zn(II), Cd(II), and Ag(I) (d 1 0 ), as well as metal free N-alkyl-1,10-phenanthrocyanines [32][33][34][35][36][37][38][39][40][41][42]. The developed synthetic approaches are based on metal-promoted direct CH-CH coupling of coordinated and quaternized 1,10-phenanthrolines.…”

“…Of parcticlar interest in terms of DNA probe applications are electron-rich supramolecular 1,10-phenanthrocyanines of transition metals, coordination compounds of a new cyanine structural class [32][33][34][35][36][37][38][39][40][41][42]. They can be considered as potential pharmacologic agents of a new generation, which form templates with DNA.…”