Molecular design and structural pecularities of the 3- and 4-pyridylboron-capped tris-glyoximate and tris-dichloroglyoximate iron(II) clathrochelates with apical donor groups

Zelinskii, Genrikh E.; Belov, Alexander S.; Вологжанина, Анна В.; Limarev, Ilya P.; Dorovatovskii, Pavel V.; Zubavichus, Yan V.; Lebed, Ekaterina G.; Voloshin, Yan Z.; Дедов, А. Г.

doi:10.1016/j.poly.2018.12.031

Polyhedron

2019

DOI: 10.1016/j.poly.2018.12.031

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Molecular design and structural pecularities of the 3- and 4-pyridylboron-capped tris-glyoximate and tris-dichloroglyoximate iron(II) clathrochelates with apical donor groups

Genrikh E. Zelinskii

Alexander S. Belov

Анна В. Вологжанина

et al.

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Cited by 5 publications

(2 citation statements)

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“…Furthermore, the lateral groups on the cage complex can be varied substantially. , For the present study, we have used four different cage structures, including chiral 2d , but more variations can be envisioned. It might also be possible to incorporate cages with dichloroglyoximate ligands, which could be used for postsynthetic modifications via nucleophilic substitution reactions. , …”

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Incorporation of Clathrochelate-Based Metalloligands in Metal–Organic Frameworks by Solvent-Assisted Ligand Exchange

Planes

Schouwink

Bila

et al. 2020

Crystal Growth & Design

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Iron(II) cage complexes with terminal 4-pyridyl groups can be incorporated in metal–organic frameworks (MOFs) via solvent-assisted ligand exchange (SALE). Paddle-wheeled MOFs with N,N′-di-4-pyridylnaphthalenetetracarboxydiimide pillars were used as starting materials. Pillar exchange was nearly quantitative, despite the fact that the cage complexes are long (∼15 Å) and sterically demanding. The reactions provide products of high crystallinity, and the structures of daughter MOFs were determined by single crystal X-ray diffraction. The crystallographic analyses showed that some of the SALE experiments led to topological changes of the MOF structures.

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“…It might also be possible to incorporate cages with dichloroglyoximate ligands, which could be used for postsynthetic modifications via nucleophilic substitution reactions. 45,68 ■ ASSOCIATED CONTENT * sı Supporting Information…”

mentioning

confidence: 99%

Incorporation of Clathrochelate-Based Metalloligands in Metal–Organic Frameworks by Solvent-Assisted Ligand Exchange

Planes

Schouwink

Bila

et al. 2020

Crystal Growth & Design

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Boronate Ester‐Capped Helicates

Giraldi

Depallens

Ortiz

et al. 2020

Chemistry A European J

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Triple‐stranded helicates were obtained by metal‐templated multicomponent reactions of bispyridyloxime ligands with arylboronic acids. The helicates feature two hexa‐coordinated MII ions (M=Fe, Zn, or Mn), which are embedded in a macrobicyclic ligand framework, and two arylboronate ester capping groups. The latter can be used to introduce functional groups such as pyridines, aldehydes, nitriles, and carboxylic acids in apical position. The functionalized helicates have the potential to be used as nanoscale building blocks for more complex assemblies, as evidenced by the synthesis of a 3 nm‐sized trianglimine.

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Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

et al. 2021

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Molecular design and structural pecularities of the 3- and 4-pyridylboron-capped tris-glyoximate and tris-dichloroglyoximate iron(II) clathrochelates with apical donor groups

Cited by 5 publications

References 15 publications

Incorporation of Clathrochelate-Based Metalloligands in Metal–Organic Frameworks by Solvent-Assisted Ligand Exchange

Incorporation of Clathrochelate-Based Metalloligands in Metal–Organic Frameworks by Solvent-Assisted Ligand Exchange

Boronate Ester‐Capped Helicates

Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

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